自从1913年Rosenheim和Bilecki首次报道含有机基团的杂多化合物后,直到1978年第一个具有Keggin结构杂多阴离子的有机衍生物才被研制出来,此后文献上相继报道了各种类型杂多阴离子的有机衍生物。由于它们是一类十分优秀的催化剂,可用于电子显微镜的染色剂、光电有机调色剂、标记有机化合物的特殊官能团或大分子的生物活性部分,在印 Since Rosenheim and Bilecki first reported organic group-containing heteropoly compounds in 1913, the first organic derivatives with Keggin structure heteropolyanions were not developed until 1978. Since then, various types of heteropoly compounds have been reported in the literature Anionic organic derivatives. Because they are a very good class of catalysts, they can be used in electron microscopy dyes, optoelectronic toners, special functional groups for labeling organic compounds or bioactive parts of macromolecules,