CYCLOPHANE相关论文
Stable organic diradicals have received a considerable attention owing to their intriguing solid-state properties....
The most widely studiedof imidazoliumcyclophanebecause of the positive charge on the imidazolium,which makes the C-H act......
Paracyclophane can possess planar-chirality depending on the length of ansa-chain and substituents on the benzene ring.T......
本文通过对荣华二采区10...
用2,6-二(咪唑甲基)-4-氯苯酚分别与邻、间、对-二(溴甲基)苯或2,6-二(溴甲基)吡啶反应,合成了一类新型的取代酚-咪唑Weng型环番。所有化合物均被MS,^1HNMR,IR和元素分析......
以氯代环氧丙烷和氢醌为原料合成了一系列含有丙三醇单元的低聚酚醚链化合物。采用变温核磁共振技术研究了低聚酚醚链与缺π电子联......
基于联萘衍生物手性构型高度稳定以及联萘结构中2个萘平面的两面角可以在一定范围内张合的特点。分别以光学活性的(R)和(S)-2,2’-二乙......
基于联萘衍生物手性构型高度稳定的特点,以光学活性的(R)-2,2'-二乙炔基-1,1'-联萘为模板,设计了3个有趣的拓扑环芳分子——含有4个手性联......
螺旋理论认为,几乎所有的有机化合物结构中都存在螺旋,螺旋结构是导致旋光性的根本原因.左手螺旋左旋;右手螺旋右旋.化合物的总旋光方向......
环番作为一种人工合成受体,具有多个活性位点和一定的空腔尺寸等诸多特性,因而具有分子识别、光学性质、催化活性和药物活性等诸多......
以3,5-二甲基苯酚为原料,经4步反应合成了1,1'-【{5-[3-(乙酰硫基)丙氧基]-1,3-亚苯基}双(亚甲基)】双{[(4,4'-联吡啶)-1-鎓]}二六氟磷酸盐......
芘番是环番的一种类型,其不仅具有芘的理化性质,同时也具有环番的理化性质.对于芘番的合成,国内鲜有报道.就芘番的定义、结构、合......
介绍了环蕃化合物的结构特征及在超分子化学研究中的新进展,重点综述了多种新型环蕃化合物的合成及应用、新型环蕃化合物对分子离......
研究环芬化合物修饰电极的制备、电化学性质及对NADH的电催化作用。用光谱电化学法和红外等手段对修饰前后的环芬化合物进行了表征......
Two novel dithia[3.3]metacyclophanes substituted with ethynyl groups were synthesized as small-sized metacyclophanes fro......
Two novel dithia[3.3]metacyclophanes substituted with ethynyl groups were synthesized as small-sized metacyclophanes fro......
由三甘醇和四甘醇出发,经炔丙基烷基化、Mitsunobu反应和Eglinton偶联反应3步合成了2个含均苯四甲酸二酰亚胺结构单元以及丁二炔结......
基于4,4′-联吡啶基础上构筑的缺电子环蕃是超分子化学的一个重要组成部分,由于其在光物理、光化学和电化学方面的可控性变化,使其成......
Dendritic cyclophane tetramer and octamer were prepared by aminolysis of succinimidyl ester derivative of tetraaza [6.1.......
A water-soluble cyclophane (1) having poly(ethylene glycol) (PEG) moieties has been prepared from a tetraazide-functiona......
A cationic water-soluble cyclophane (1a) having a rhodamine moiety as a red-fluorescence fluorophore was prepared by rea......
A cationic branch-type cyclophane tetramer (1a) was synthesized by introducing three Boc-protected cyclophane derivative......
A cationic branch-type cyclophane tetramer (1a) was synthesized by introducing three Boc-protected cyclophane derivative......
本文综述了水溶液和有机溶液中环番作为人工受体包结有机分子的行为,重点综述了功能化环番作为人工番的研究进展。......
Anion can be identified by pyromellitic imide-azacyclophane which is one of the host compounds.This article investigated......