norbornene相关论文
Trifunctionalization of Aryl Iodides with Two Distinct Nitrogen and Carbon Electrophiles by Palladiu
Herein,we report a highly chemo-and regioselective vicinal trifunctionalization of aryl iodides by palladium/norbornene ......
SYNTHESIS AND CHARACTERIZATION OF THE FULLY FUNCTIONALIZED PHOTOREFRACTIVE POLYMERS VIA RING-OPENING
Fully functionalized photorefractive polymers have attracted much attention in recent years.While the synthesis of chrom......
PM-PP-63:Neutral Half Sandwich Cyclopentadienyl Nickel Complexes Synthesis and Their Olefin Polymeri
...
IE-IL08:Precision Polymerization of 1-Alkene and Norbornene Using ansa-Fluorenylamidodimethyltitaniu
...
The transition-metal-catalyzed copolymerization of olefins with polar comonomers is a direct strategy to access polar-fu......
以3-碘代色酮、降冰片烯、新戊酸钯和三(4-甲氧苯基)膦为原料,通过“一锅法”合成了一种含色酮骨架的新型Pd(II)配合物,其结构经1H......
Quinolinyl Imidazolidin-2-imine Nickel Catalyzed Efficient Copolymerization of Norbornene with para-
A series of novel quinolinyl imidazolidin-2-imine nickel complexes with different substituents on the imidazolidin-2-imi......
Crystal Structure and Polymerization Activity of Bromo-(2-diphenylphosphino-N-(2-oxybenzylidene)-ani
本文通过对荣华二采区10...
采用常压脱己烷、减压脱轻、减压脱重组分三步精馏法有效地从乙叉降冰片烯(ENB)残液中回收ENB产品,和目前ENB回收工艺相比,解决了E......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
The ring opening metathesis polymerization of cyclic monomers is relatively a newcomer to the field of polymer chemistry......
VINYL POLYMERIZATION OF NORBORNENE CATALYZED BY[2-(2-BENZIMIDAZOLYL)-6-((1-ARYLIMINOETHYL)PYRIDYL)]N
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Efficient Addition Polymerization of Norbornene with Polar Norbornene Derivatives by Neutral Nickel(
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
研究了BP/THF引发体系引发降冰片烯(NB)与马来酸酐(MA)自由基光聚合性能。考察了单体和引发剂浓度、第三单体的加入和氛围对共聚合......
A series of salicylaldimines, synthesized in high yield via microwave-assisted condensation of salicylaldehyde and 2-alk......
VINYL POLYMERIZATION OF NORBORNENE CATALYZED BY[2-(2-BENZIMIDAZOLYL)-6-((1-ARYLIMINOETHYL)PYRIDYL)]N
The catalytic system of[2-(2-benzimidazolyl)-6-((1-arylirninoethyl)pyridyl)]nickel chloride/MAO (methylalu-minoxane)was ......
用水杨醛亚胺镍/MMAO催化降冰片烯聚合获得了热稳定、高分子量、可溶性的加成聚合产物. Al、Ni摩尔比、单体浓度、反应温度与时间......
采用两种苯胺邻位取代基是二苯甲基的α-二亚胺镍配合物作为主催化剂,甲基铝氧烷为助催化剂,实现了降冰片烯均聚合及其与1-己烯的......
在干燥非质子性溶剂中,以3,6-桥-亚甲基-1,2,3,6-四氢邻苯二甲酰氯与N-(3-氨基丙基)咪唑和1-氨基-4-甲基哌嗪为原料,合成了两种降冰......
首次用Pd(OAc)2-1,4∶3,6-双脱水-2,5-二(二苯基膦)-L-艾杜糖醇(DDPPI)-p-TsOH催化体系对降冰片烯进行了不对称氢酯基化反应,获得了较好的结果.考察了手性膦配体的结构以及磷原......
通过改变相应的条件,研究了在低温下合成降冰片烯的可能性。为了得到较多的目标产品,对其生成条件(反应温度、乙烯初压、反应时间)进行......
使用内循环式无梯度反应釜他环戊二烯与乙烯在相条件下进行环加成反应生成降冰片烯的动力学参数。无梯度反应釜出口组成组成由气相......
锆茂均相催化体系催化乙烯与降冰片烯共聚合的研究谢光华,王金梅,张盛庆(中国科学院化学研究所,北京,100080)关键词锆茂均相催化体系,乙烯,降冰片......
本文通过一步法制备了新型的苯胺基肟类中性钯催化剂,并通过核磁氢谱、核磁碳谱、元素分析对相应的配体和催化剂结构进行了测试表......
研究了Nd(naph)3-Al(i-Bu)3(naph为环烷酸)催化降冰片烯(NB)与甲基丙烯酸丁酯(BMA)共聚反应的条件及其催化剂钕铝比的影响.结果表明:稀土催化......
研究了Nd(naph)3-Al(i-Bu)3(naph=环烷酸)催化降冰片烯(NB)与甲基丙烯酸特丁酯(TBMA)共聚反应条件、催化剂用量及钕铝比影响.并用核磁共振、......
吡啶脒基镍配合物在助催化剂甲基铝氧烷(MAO)作用下催化降冰片烯聚合。考察了催化剂结构中电子效应与位阻效应对聚合反应的影响,研究......
使用[t-BuNSiMe2(3,6-t-Bu2Flu)]TiMe2(A),[(1-金刚烷胺基)NSiMe2(3,6-t-Bu2Flu)]TiMe2(B),[t-BuNSiMe2(3,6-OMe2Flu)]TiMe2(C),[(......
以偶氮二异丁腈(AIBN)为自由基引发剂,以降冰片烯(NBE)、N-环已基马来酰亚胺(CHMI)、马来酸酐(MA)和环已胺(CHA)为主要原料,分别利用降冰片烯、......
通过环状烯烃双键打开,首尾相接形成聚合物的方法,设计合成了含有季铵阳离子作为功能化基的降冰片烯衍生物单体QRPh NB,通过开环异......
为了提高阴离子交换膜的离子传导率,本文以降冰片烯二酸酐为原材料,单体中引入两个官能团提高单位体积内离子交换容量制备了阴离子......
Simple and efficient stereo-selective synthesis of exo-5-norbornene-2-carboxylic acid (NBCA) is reported. Preliminary st......
Crystal Structure and Polymerization Activity of Bromo-(2-diphenylphosphino-N-(2-oxybenzylidene)-ani
The title compound,bromo-(2-diphenylphosphino-N-(2-oxybenzylidene)-aniline)- nickel,was synthesized by simple condensati......
Synthesis, Crystal Structure and Norbornene Polymerization of a Palladium( II) Complex Based on Phen
The title complex N,O-bis{2-[[(2,6-benzhydryl-4-methylphenyl)imino]-methyl]- phenol}-pal 1 adium(II)(C8oH64N202Pd) has b......