Transition metal oxides (Co3O)4, CoO, NiO, MnO, et al.) are accounted as potential anode materials for high performance Li-ion batteries (LIBs).And the traditional thermal treatment method is usually performed to synthesize them through the decomposition reactions of precursors including MeCO3,Me(OH)2 and MeC2O4 (Me =Co, Ni and Mn, et al.) [1].