硒蒸发温度对共蒸发法制备Cu2ZnSnSe4太阳电池的影响

来源 :第13届全国博士生学术年会——新能源专题 | 被引量 : 0次 | 上传用户:xyhai110
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研究了不同硒蒸发温度对蒸发法制备Cu2ZnSnSe4(CZTSe)太阳电池的影响,当Se温较低时,低的硒蒸发速率导致初始阶段Zn元素不易与Se反应生成稳定的ZnSe,影响了CZTSe在闪锌矿的ZnSe的外延生长,薄膜最终没有择优取向.当Se温较高时,CZTSe薄膜呈(112)择优,但过高的硒蒸发速率较少了初始阶段铜过量的时间,由于铜过量对CZTSe薄膜有一定促进生长的作用,较短的铜过量时间造成CZTSe薄膜结晶质量稍微变差.在较合适的230℃硒蒸发温度条件下制备出效率为2.32%(有效面积0.34cm2)未经过后硒化处理的CZTSe太阳电池.
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