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  5. Enhancement of Selectivity for Tandem Reactions through Adjusting Micro-environment of Metal Complex

Enhancement of Selectivity for Tandem Reactions through Adjusting Micro-environment of Metal Complex

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户：yanguoke
【摘 要】
：
Ruthenium(Ⅱ)N-heterocyclic carbene(NHC)complexes bearing pentamethylcyclopentadienyl ligands(Cp*)have been proven to be highly efficient in racemization of chiral alcohols.1 During our investigation o
【作 者】
：
Cao Hui Jing-Fan Zhang Xiu-Feng Hou 
【机 构】
：
Department of Chemistry Fudan University,Shanghai,200433
【出 处】
：
第九届全国无机化学学术会议
【发表日期】
：
2015年7期
【关键词】
：
selectivity tandem DKR heterogeneous immobilization ruthenium-NHC 
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　　Ruthenium(Ⅱ)N-heterocyclic carbene(NHC)complexes bearing pentamethylcyclopentadienyl ligands(Cp*)have been proven to be highly efficient in racemization of chiral alcohols.1 During our investigation of the catalytic performance of a cymene ruthenium NHC complex,2 we found that it was highly active for racemization of optically pure alcohols.
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