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The mechanism of surface modification on polymer by plasma technology is dissertated.Several principles of surface modification on polymer by plasma are summarized.The surface modification on polymer by plasma technology is reviewed.There are three ways using plasma technology to modify the surface properties of polymer materials, which are plasma surface treatment, plasma polymerization and plasma graft copolymerization.Plasma technology has been applied in polymer material surface modification more and more.The surface modification of the plasma graft copolymerization is emphasized.