【摘 要】
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Supramolecular polymer networks are formed by non-covalent associative interactions between polymer chains.The reversibility of the crosslinks leads to a wide range of potential applications of these
【机 构】
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School of Mathematical and Physical Sciences,University of Reading Whiteknights,RG6 6AX Reading,UK
【出 处】
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Seventh International Symposium On Engineering Plastics (第七届
论文部分内容阅读
Supramolecular polymer networks are formed by non-covalent associative interactions between polymer chains.The reversibility of the crosslinks leads to a wide range of potential applications of these physical networks, such as self-healing and stimuli-sensitive materials.In this work we present computational studies of supramolecular networks formed by unentangled telechelic chains with sticky end monomers of controlled fimctionalities.By using hybrid molecular dynamics/Monte Carlo simulations, the topological, dynamical and theological behavior of the networks are investigated as functions of the sticky monomer bonding energy, association kinetics and the polymer chain length.
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