酰腙基席夫碱Zn(Ⅱ)配合物的合成和力致发光变色性质

来源 :中国化学会第十届全国无机化学学术会议 | 被引量 : 0次 | 上传用户:asd03071128
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  力致发光变色(Mechanochromic luminescent,MCL)材料是一类荧光随外力刺激而改变的材料,广泛应用于传感器、记忆芯片、安全油墨等领域[1]。我们合成了两个酰腙基席夫碱Zn(Ⅱ)配合物[Zn(HL1)2Py2](1)和[Zn(L2)2Py2](2)(H3L1:N-(2-羟基-1-苯次甲基)-3-羟基-2-萘酰腙,H3L2:N-(2-羟基-1-苯次甲基)-2-萘酰腙),测定了它们的晶体结构。
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