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  5. DFT Calculations of the Rhodium-Catalyzed Oxidative C-H Allylation of Benzamides with 1,3-Dienes by

DFT Calculations of the Rhodium-Catalyzed Oxidative C-H Allylation of Benzamides with 1,3-Dienes by

来源 :第十三届全国量子化学会议 | 被引量 : 0次 | 上传用户：SongSan
【摘 要】
：
Allylmetal species are important intermediates in organic synthesis.[1] Recently, Stamatis E. Korkis and co-workers[2] first reported allyl-to-allyl 1,4-Rh(Ⅲ) migration in the oxidative C-H allylation
【作 者】
：
Shaojing liu Fengyue Zhao Yaping Li Shumin Han Tao Liu Zhangyu Yu 
【机 构】
：
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, Shandong Province
【出 处】
：
第十三届全国量子化学会议
【发表日期】
：
2017年10期
【关键词】
：
reaction mechanism DFT Calculations 
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　　Allylmetal species are important intermediates in organic synthesis.[1] Recently, Stamatis E. Korkis and co-workers[2] first reported allyl-to-allyl 1,4-Rh(Ⅲ) migration in the oxidative C-H allylation of benzamides with 1,3-dienes which is different to the characteristic reaction we known that 1,3-transposition of the metal from one end of the allylic fragment to the other.
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