Fabrication of Xylose Hydrochar Microspheres Supported Palladium Nanocomposites for Suzuki-Miyaura C

来源 :The 6th International Conference on Nanoscience and Technolo | 被引量 : 0次 | 上传用户:syzy3106jiege
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  A carbon-rich solid product of hydrochar microspheres(C)has been prepared by the hydrothermal carbonization of xylose at 180℃ for 12 h,which possesses a core-shell structure consisting of a highly aromatic nucleus and a hydrophilic shell containing a high concentration of reactive oxygen functional groups,for example,hydroxyl,phenolic,carbonyl and carboxylic.[1] These properties make it has great ability to stabilize metal particles and also it is an ideal candidate for chemical modification by 3-mercaptopropyl trimethoxysilane. Thiol groups on hydrochar microspheres enable the modulation of Pd coordination, giving rise to strongly-ligated Pd-C-SH nanocomposites, obtained by the interaction of thiol arms with palladium nanoparticles.
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