Both copper and iron are called base metals and played important roles in the post-anaerobic evolution of nature and exists in a large number of enzymes.
A 3D metal-organic framework,[Zn(PAM)(4-bpdb)] ·DMF(1),has been constructed with aπ- electron-rich ligand 4,4-methylenebis(3-hydroxy-2-naphthalenecarboxylic acid)(PAM)and 1,4-bis(4-pyridyl)-2,3-diaza-
Polynuclear lanthanide hydroxide polymers are a class of intriguing substances with varieties of potential applications ranging from luminescent and magnetic materials to homogeneous catalysis.
In this paper,We synthesized five novel 1D isostructural Zn(Ⅱ)-lanthanide(Ⅲ)heterometallic complexes[LnZn(L)(H2O)(Cl2)]·2DMA·2H2O(Ln=Nd(1),Eu(2),Tb(3),Dy(4),Gd(5))and synthesized seven 1D heterometall
As an exciting new branch of supramolecular chemistry,the study of the assembly and reactivity of nanosized clusters has attracted great interest.[1-2] In this paper,we synthesized a Fe5 cluster,[Fe5(
Polynuclear mental complexes of transition mental have grown in the past decade in relation to their potential applications associated with such molecular magnetic properties.
Recently,the tight focuisng properties of vector optical fileds have attracted a great attention,and many applications have been found in areas such as near-field optics,nonlinear optics,quantum optic