【摘 要】
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Photochemical reaction of cyclohexyl phenyl ketone (1) leads either to intra-or intermolecular hydrogen abstraction product (2 and 3 respectively), and 3 consists of pair of enantiomers.Two types of c
【机 构】
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Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Phys
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Photochemical reaction of cyclohexyl phenyl ketone (1) leads either to intra-or intermolecular hydrogen abstraction product (2 and 3 respectively), and 3 consists of pair of enantiomers.Two types of chiral hexagonal crystals were prepared and used as chiral microreactors for the photochemical reaction of 1: one formed by 1-tetradecyl-3-methylimidazolium bromide/p-xylene/H2O and modified with a chiral inductor,another formed by S-3-hexadecyl-1-(1-hydroxy-propan-2-yl)-imidazolium bromide/p-xylene/H2O, While in the former type of micro-reactor no enantioselectivity for 3 was observed, evident enantioselectivity was achieved in the latter mocroreactor.
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