Gold and Palladium Hetero-bis(NHC)Complexes:Characterizations,Correlations and Ligand Redistribution

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  Gold(Ⅰ)hetero-(NHC)complexes are given much less attention[1] despite the blooming of gold carbene chemistry.In this work,a range of hetero-(NHC)complexes [Au(iPr2-bimy)(NHC)]X(X = BF4 or PF6)have been synthesized using [Au(Oac)(iPr2-bimy)] as a new and versatile complex precursor.
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