可见光催化产生杂原子自由基的反应研究

来源 :第十二届全国物理有机化学学术会议 | 被引量 : 0次 | 上传用户:quanruihongjing
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可见光催化是一种清洁高效的反应研究手段,同时因为光催化和传统的加热手段在科学本质上的不同,也产生了许多新的化学[1].本课题组围绕氢气开展脱氢偶联[2]及氮杂环脱氢的研究[3].我们发展了可见光和金属钴协同催化的室温进行的氮杂环脱氢反应,同时利用该方法实现了温和条件下氮杂环化合物的脱氢和加氢的催化循环,并开展了相关的机理研究,展示了氮杂化化合物在储氢材料领域的潜在应用,是其应用到储氢材料领域研究思路的重要突破(Figure 1).
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