Shape amphiphiles usually refer to molecules composed of segments with distinct shapes.1 These shape amphiphiles have rich phase behaviors and unusual hierarchal structures.Thus the design of new shape amphiphiles is essential to achieve hierarchal structures and functional materials.Hexa-peri-hexabenzocoronenes(HBCs)with different substitution patterns are known to self-assemble into columnar liquid crystalline phases in bulk and into nanotubes in solution.2,3 In addition,HBCs have the highest one-dimensional charge-transfer mobility among discotic liquid crystals.Polyhedral oligomeric silsesquioxane(POSS)with a cubic shape is perhaps the smallest nanoparticle.And the surface groups of POSS can be easily modified via various reactions.4 Thus.covalently linking HBC and POSS may lead to interesting hierarchical structures.