The activated alumina as a catalyst carrier were widely used in automotive exhaust catalysts under high temperature,such as,petroleum refining catalysts,hydrogenation and hydrodesulfurization catalyst carrier in China and abroad.γ-Al2O3 was the catalyst carrier that was the most widely used and the best carrier of improved specific surface area .However,the activation of the coating consisted of γ-Al2O3 were usually transformed into α-Al2O3 at 800 oC,causing increased density,reduced specific surface area,and the collapse result of pore structure.While the temperature reached 1200 oC,activation of coating detached from the carrier,the resistance of flowing gas increased,catalytic activity decreased.Addition of La2O3 stabilized the γ-Al2O3 crystal structure,which would keep the activation stability of coating at a high temperature and inhibit activity loss.The activated alumina carrier treated with the solid-pore-expanding agent containing [La(EDTA)]-that synthesized using solid and solid-hybrid approach with the thermal stabilizer lanthana and EDTA at the high-temperature had a 10-30 μm large pore porous network-like structure,after alumina was calcined at 1200 oC for 1 h.The specific surface area of four specimen were beyond 120 m2/g,while the sample specific surface area of x([La(EDTA )]-)=1% was up to 150.36 m2/g. The activated alumina as a catalyst carrier were widely used in automotive exhaust catalysts under high temperature, such as, petroleum refining catalysts, hydrogenation and hydrodesulfurization catalyst carrier in China and abroad. Γ-Al2O3 was the catalyst carrier that was the most widely used and the The best carrier of improved specific surface area. However, the activation of the coating consisted of γ-Al2O3 were transformed into α-Al2O3 at 800 oC, causing increased density, reduced specific surface area, and the collapse result of pore structure. Whilst the temperature reached 1200 oC, activation of coating detached from the carrier, the resistance of flowing gas increased, catalytic activity decreased. Addition of La2O3 stabilized the γ-Al2O3 crystal structure, which would keep the activation stability of coating at a high temperature and inhibit activity loss. activated alumina carrier treated with the solid-pore-expanding agent containing [La (EDTA)] - that synthesized using solid and solid-hybrid approach with the thermal stabilizer lanthana and EDTA at the high-temperature had a 10-30 μm large pore porous network-like structure, after alumina was calcined at 1200 oC for 1 h. the specific surface area of ​​four specimen were beyond 120 m2 / g, while the sample specific surface area of ​​x ([La (EDTA)] -) = 1% was up to 150.36 m2 / g.