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Cp_2ZrCl(S_2CNBz_2) is a five-coordinate bent zirconocene in which the dibenzyldithiocarbamate is a bidentate ligand (Zr-Cl 2.549(1)A; Zr-C 2.489-2.533; Zr-S 2.667(1), 2.734(1); Zr-Cl-S1 137.6(1)~o; Zr-Cl-S2 73.3(1)~o).
Cp 2 ZrCl (S 2 CNBz 2) is a five-coordinate bent zirconocene in which the dibenzyldithiocarbamate is a bidentate ligand (Zr-Cl 2.549 (1) A; Zr-C 2.489-2.533; Zr-S 2.667 -Cl-S1 137.6 (1) ~ o; Zr-Cl-S2 73.3 (1) ~ o).