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我们曾对二价的过渡金属与18—冠—6配合物的合成与表征进行研究。本文用凝胶法得到标题的两种三价过渡金属离子的组成类似韵配合物晶体,并对它们进行了组成分析和多项物理性质的测试和表征。而其中的铬配合物作者已进行X射线单晶结构分析。
We have studied the synthesis and characterization of divalent transition metal complexes with 18-crown-6. In this paper, two title trivalent transition metal ions obtained by the gel method are similar in composition to the crystal of rhyme complexes, and their composition analysis and testing and characterization of a number of physical properties are performed. One of the chromium complexes has been X-ray single crystal structure analysis.