【摘 要】
：
The trinuclear complex bis(18-crown-6)thallium tetracyanoplatinate [Tl2(18-crown- 6)2Pt(CN)4]·2H2O was prepared and its structure was determined by X-ray diffr
【机 构】
：
Department of Chemistry,Department of Chemistry and Chemical Engineering
论文部分内容阅读
The trinuclear complex bis(18-crown-6)thallium tetracyanoplatinate [Tl2(18-crown- 6)2Pt(CN)4]·2H2O was prepared and its structure was determined by X-ray diffraction analysis. The compound (C28H52N4O14PtTl2, Mr = 1272.57) crystallizes in monoclinic, space group P21/n with a = 10.5180(10), b = 8.6162(8), c = 21.118(2) (A), β = 92.577(2)°, V = 1911.9(3) (A)3, Z = 2, Dc = 2.211 g/cm3, F(000) = 1200, μ = 12.123 mm-1, R = 0.0181 and wR = 0.0427. The linearly arranged three metals are sandwiched by two 18-crown-6 molecules.
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