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合成了Zn、Pb两个系列卟啉金属配合物12个,其中6个为未见文献报道的新化合物,用元素分析、IR、UV、~1HNMR、MS确证了其结构。总结了Zn、Pb与卟啉类配体配合的IR、UV、~1H NMR判据。研究了这两个系列化合物的液晶性能,发现9个化合物具有液晶性。
Twelve series of porphyrin complexes were synthesized, of which six were new compounds not reported in the literature. Their structures were confirmed by elemental analysis, IR, UV, ~ 1HNMR and MS. The IR, UV and 1H NMR data of Zn and Pb complexes with porphyrin ligands were summarized. The liquid crystal properties of the two series of compounds were investigated and nine compounds were found to have liquid crystallinity.