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经典离子极化理论认为离子极化率随极化力增大而变小,但确有一类极化率随极化力增大而变大的阳离子。为同时解释这两种事实,文中提出离子极化作用的配位键模型,并对其合理性作了讨论。
The classical theory of ion polarization suggests that the ion polarizability decreases with increasing polarizability, but there is indeed a class of cations with increasing polarizability with increasing polarizability. In order to explain both of these facts at the same time, the coordinate bond model of ion polarization is proposed and its rationality is discussed.