在广泛使用表面活性剂的今天,将聚合物离子选择电极用于测量表面活性剂,是一个有实用价值的课题,可望实现对环保工程中的监控和工业流程中的质量控制.人们曾对此进行了大量的工作,但对有些问题的看法至今尚无定论.为此,我们研制了几种膜电极,分别对Cl~-,Ba~(2+)和一系列阴离子、非离子表面活性剂进行测试,比较了各自响应规律的异同点,并从理论上对响应机理进行了探讨. Today, the widespread use of surfactants, polymer ion selective electrode for the measurement of surfactants, is a practical project, is expected to achieve environmental monitoring and industrial processes in the quality control. A great deal of work has been done on this topic, but there is still no conclusion on some problems.For this reason, we have developed several kinds of membrane electrode, respectively, for Cl ~ -, Ba ~ (2+) and a series of anionic, nonionic surfactant Agents were tested, the similarities and differences between their respective response laws were compared, and the response mechanism was discussed theoretically.