【摘 要】
：
An iron(Ⅲ)-catalyzed selective oxidation of 5-HMF to 2,5-DFF in air at room temperature was developed.This approach gives 2,5-DFF with good selectivity and yie
【机 构】
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Anhui Province Key Laboratory of Biomass Clean Energy, Department of Chemistry, University of Scienc
【出 处】
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Chinese Chemical Letters
论文部分内容阅读
An iron(Ⅲ)-catalyzed selective oxidation of 5-HMF to 2,5-DFF in air at room temperature was developed.This approach gives 2,5-DFF with good selectivity and yields. Additionally, a two-step process was developed for the oxidation of 2,5-DFF to 2,5-FDCA at remarkably high substrate concentrations. This work demonstrates unequivocally the great potential of iron as a cheap and earth-abundant catalyst for the development of new protocols for the conversion of biomass to value-added chemicals.
An iron (III) -catalyzed selective oxidation of 5-HMF to 2,5-DFF in air at room temperature was developed. This approach gives 2,5-DFF with good selectivity and yields., A two-step process was developed. for the oxidation of 2,5-DFF to 2,5-FDCA at remarkably high substrate concentrations. This work demonstrates unequivocally the great potential of iron as a cheap and earth-abundant catalyst for the development of new protocols for the conversion of biomass to value-added chemicals.
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