,Effect of an electric field on the electrocaloric response of ferroelectrics

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The electrocaloric effect of the model ferroelectric BaTiO3 was investigated using phenomenological theory. The results indicate that the applied electric field strength is a key factor for the induced electrocaloric response and there are two distinguishing electrocaloric responses. When a moderate electric field is applied, the electrocaloric temperature variation is small but the electrocaloric strength is high. In contrast, the electrocaloric temperature variation is large but electrocaloric strength is low when a very high electric field is applied. These results are consistent with the experimental observations on BaTiO3 based bulk and thin film ferroelectric materials.
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