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A novel heterobimetallic coordination polymer, {(NH4)2[Cd(H2O)Fe(CN)6]}n 1, has been synthesized by using the slow diffusion method and structurally characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group P21/n, a = 7.4202(16), b = 14.939(3), c = 10.868(2) A and ? = 91.660(3)A. For 1, five CN groups of Fe(CN)6]4- are involved in bridging. The polymer displays a 3D open microporous framework with 5-connected uninodal(46.64) topology.
A novel heterobimetallic coordination polymer, {(NH4) 2 [Cd (H2O) Fe (CN) 6]} n1, has been synthesized by using the slow diffusion method and structurally characterized by elemental analysis, IR spectroscopy and single- ray diffraction. The crystal crystallizes in the monoclinic system, space group P21 / n, a = 7.4202 (16), b = 14.939 (3), c = 10.868 (2) A and? = 91.660 (3) five CN groups of Fe (CN) 6] 4- are involved in bridging. The polymer displays a 3D open microporous framework with 5-connected uninodal (46.64) topology.