Oxidation of Hecogenin and Diosgenin Derivatives with Dimethyldioxirane

来源 :中国化学快报：英文版 | 被引量 : 0次 | 上传用户：rommer006

【摘要】

：

Diacetyl derivative of hecogenin 1 was oxidized to unsaturated ketone 5 via allylic alcohol 3 when it reacted with dimethyldioxirane (DMDO). The structure of 3

【作者】

：

BaoKunZHU HongBinZHANG YuShunZ

【机构】

：

TheSchoolofPharmacy,TheSchoolofChemistry

【出处】

：

中国化学快报：英文版

【发表日期】

：

2005年2期

【关键词】

：

龙舌蓝皂苷配基薯蓣皂苷配基二氧甲基双环氧乙烷氧化物 X射线分析化学结构 Oxidation dimethyldioxirane hecogenin

【基金项目】

：

International Cooperation Division of Yunnan Provincial Science & Technology Department，Yunnan University

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Diacetyl derivative of hecogenin 1 was oxidized to unsaturated ketone 5 via allylic alcohol 3 when it reacted with dimethyldioxirane (DMDO). The structure of 3 was confimed by X-ray crystal analysis and the highly regioselectivity of DMDO to different ole

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Oxidation of Hecogenin and Diosgenin Derivatives with Dimethyldioxirane

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