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A new Ag（I） coordination polymer,{[Ag（l,3-BIP）（H2O）][Ag（l,3- BIP）（PMA）0.5·-4H2O}n（PMA = 1,2,4,5-benzenetricarboxylic acid,1,3-BIP = l,3-bis（imidazole）propane）,have been synthesized and characterized by single-crystal X-ray diffraction,powder XRD,FTIR