研究了在有机胶凝剂中掺杂的席夫碱化合物的结构和性质.实验发现,虽然席夫碱分子单独不能在有机溶剂中形成凝胶,当其与一种胶凝剂N,N′-双十八烷基-L-Boc-谷氨酸混合时,它们在二甲基亚砜或甲苯中形成透明的有机凝胶.与相应的溶液相比,观察到在有机凝胶中的荧光增强现象,并且这一增强与席夫碱的结构有密切关系.在二甲基亚砜的有机凝胶中,观察到带有长烷基链的席夫碱具有诱导手性.表明通过凝胶的形成,胶凝剂的手性能传递到带有长链的席夫碱上. The structure and properties of Schiff base compounds doped with organic gelling agents were investigated. It was found that although Schiff base alone could not form gels in organic solvents, when combined with a gelling agent N, N ’ - dioctadecyl-L-Boc-glutamic acid, they form a clear organogel in dimethyl sulfoxide or toluene.Compared with the corresponding solution, fluorescence in organogels was observed Enhance the phenomenon, and this enhancement is closely related to the structure of the Schiff’s base Schiff base with a long alkyl chain was observed to induce chirality in dimethylsulfoxide organogel, indicating that by chiral gel The formation of gelling agent hand performance transfer to Schiff base with long chains.