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室温下,18-电子体系的半夹心铑配合物Cp*Rh(L)S2C2(B10H10)(L=4-ClCH2-C6H4N(2a),4-CH3SCH2-C6H4N(2b))可以通过16-电子体系的半夹心铑配合物[Cp*Rh[S2C2(B10H10)]与吡啶衍生物合成。化合物通过IR、1HNMR和元素分析进行了表征,并用X-射线单晶衍射测定了配合物2a和2b的单晶结构。
The half-sandwich rhodium complexes Cp * Rh (L) S2C2 (B10H10) (L = 4-ClCH2-C6H4N (2a) and 4-CH3SCH2-C6H4N (2b)) of 18- Of half-sandwich rhodium complex [Cp * Rh [S2C2 (B10H10)] with a pyridine derivative. The compounds were characterized by IR, 1HNMR and elemental analysis and single crystal structures of complexes 2a and 2b were determined by X-ray single crystal diffraction.