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以Fe(DMF)_6[(FeCl_2)_2MoS_4]与Et_2NCS_2Na在DMF中反应实现了三核链状簇骼向单立方烷簇骼的转化,得到了MoFe_3S_4(Et_2NCS_2)_5并测定了它的晶体结构.本文指出与配体有关的氧化还原过程及配体的配位特点对这一转化反应及其产物的影响,同时比较了由于核心氧化态的差异而造成的簇骼结构面貌的变化.
The reaction of Fe (DMF) _6 [(FeCl_2) _2MoS_4] with Et_2NCS_2Na in DMF resulted in the conversion of trinuclear chain to monascirane clusters, and the crystal structure of MoFe_3S_4 (Et_2NCS_2) _5 was obtained. In this paper, the ligand-dependent redox processes and coordination characteristics of the ligands on the conversion reaction and its products are pointed out, and the changes of the appearance of the cluster structure due to the difference in core oxidation state are also compared.