论文部分内容阅读
A three-dimensional coordination polymer,namely {[Zn_2(tzba)(dmtrz)(OH)]·3H_2O}_n(1,H_2tzba = 4-(5H-tetrazol)benzoic acid,Hdmtrz = 3,5-dimethyl-lH,l,2,4-triazole),was hydrothermally synthesized and characterized by single-crystal X-ray diffraction.It crystallizes in monoclinic system,P2_1/c space group with a = 8.018(11),b = 21.04(3),c = 11.069(14) A,β=91.26(3)°,V= 1867(4) A~3,Z = 4,D_c = 1.729 g/cm~3,F(000) = 984,μ= 2.614 mm~(-1),R(F~2 > 2σ(F~2)) =0.0612 and wR(F~2) = 0.1533.Topological analysis reveals that compound 1 is a(3,5)-connected structure with a Schlafli symbol of(4~2.6)(4~2.6~5.8~3),which is a rarely observed lhh topology.In addition,the CO_2 adsorption performance and luminescent property of 1 have also been studied.
A three-dimensional coordination polymer, namely, [Zn 2 (tzba) (dmtrz) (OH)] 3H 2 O} _n (1, H 2 zba = 4- l, 2,4-triazole, was hydrothermally synthesized and characterized by single-crystal X-ray diffraction.It crystallizes in monoclinic system, P2_1 / c space group with a = 8.018 (11), b = 21.04 = 11.069 (14) A, β = 91.26 (3) °, V = 1867 (4) A ~ 3, Z = 4 and D_c = 1.729 g / cm ~ (-1), R (F ~ 2> 2σ (F ~ 2)) = 0.0612 and wR (F ~ 2) = 0.1533.Topological analysis reveals that compound 1 is a (3,5) -connected structure with a Schlafli symbol of (4~2.6) (4~2.6~5.8~3), which is a rare observed lhh topology. In addition, the CO 2 adsorption performance and the luminescent property of 1 have also been studied.