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The nanoreactors were fabricated by reacting amphiphilic quaternary ammoniums and polyoxoperoxometalates K_n[PW_(12-x)Ti_(x-) O_(40-x)(O_2)_x](x=1,2 and 3;n = 5,7 and 9)(K_5[PW_(11)TiO_(39)(O_2)],K_7[PW_(10)Ti_2O_(38)(O_2)_2]and K_9[PW_9Ti_3O_(37)(O_2)_3]).Fourier transform infrared spectroscopy(FT-IR),transmission electron microscopy(TEM) were used to characterize the resulting samples. This kind of nanocatalysts could promote NH_4SCN’ degradation into simple inorganic compounds such as SO_4~(2-),HCO_3~- and NO_3~- only using oxygen as an oxidant under room conditions.
The nanoreactors were fabricated by reacting amphiphilic quaternary ammoniums and polyoxoperoxometalates K_n [PW 12-x Ti x- O 40-x O 2 _x] (x = 1, 2 and 3; n = 5, 7 and 9) (PW_ (11) TiO_ (39) (O_2)], K_7 [PW_ (10) Ti_2O_ (38) (O_2) _2] and K_9 [PW_9Ti_3O_ (37) (O_2) _3] This kind of nanocatalysts could promote NH_4SCN ’degradation into simple inorganic compounds such as SO_4 ~ (2 -), HCO_3 ~ - and NO_3 ~ - only using oxygen as an oxidant under room conditions.