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The complex [Cd(H2mbdpz)(N3)2]n 1 (H2mbdpz = 4,4’-methylenebis(3,5-dime-thylpyrazole)) has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis. It crystallizes in the monoclinic system, space groups C2/c with a = 22.154(5), b = 7.4835(15), c = 21.044(8), β = 115.51(3)o, V = 3148.7(17) 3, Z = 8, C11H16CdN10, Mr = 400.75, Dc = 1.691 g/cm3, μ = 1.401 mm-1, F(000) = 1599, T = 293(2) K, the final R = 0.0228 and wR = 0.0581 for 3604 observed reflections with I > 2σ(I). The structural determination revealed that the coordination environment of Cd(II) atom is a distorted octahedron consisting of two nitrogen donors of two H2mbdpz ligands and four nitrogen donors from four azide ligands. The azide moieties act as bridges in two modes: end-on (μ1,1-) and end-to-end (μ1,3-), and H2mbdpz also serves as a bridge with a bis-monodentate coordination. Both bridging ligands link the Cd(II) atoms to form a distorted two-dimensional (6,3) layer.
The complex [Cd (H2mbdpz) (N3) 2] n1 (H2mbdpz = 4,4’- methylenebis (3,5-dime- thylpyrazole)) has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis crystallizes in the monoclinic system with space groups C2 / c with a = 22.154 (5), b = 7.4835 (15), c = 21.044 (8) , β = 115.51 (3) o, V = 3148.7 , Z = 8, C11H16CdN10, Mr = 400.75, Dc = 1.691 g / cm3, μ = 1.401 mm- 1, F (000) = 1599, T = 293 (2) K, the final R = 0.0228 and wR = 0.0581 for 3604 observed reflections with I> 2σ (I). The structural determination revealed that coordination environment of Cd (II) atom is a distorted octahedron consisting of two nitrogen donors of two H2mbdpz ligands and four nitrogen donors from four azide ligands. The azide moieties act as bridges in two modes: end-on (μ1,1-) and end-to-end (μ1,3-), and H2mbdpz also serves as a bridge with a bis- monodentate coordination. Both bridging ligands link the Cd ( II) atoms to form a distorted two-dimensional (6,3) layer.