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以丙酮、乙二胺合成六甲基四氮杂大环席夫碱化合物,将其还原成四氮杂大环冠醚配体,然后再和高氯酸铜、二氰合银酸钾反应生成四氮杂大环冠醚配合物{Me6[14]N4Cu[Ag(CN)2]2}.2H2O,并用元素分析、红外光谱、紫外光谱等手段对其结构进行了表征.
Synthesis of Hexamethyltetrazole Schiff Base Compound with Acetone and Ethylenediamine and Its Reduction to Tetraazacyclo Crown Ether Ligand, and then Reaction with Copper Perchlorate and Potassium Dicyanocyanurate The structure of tetraaza macrocyclic crown ether complex {Me6 [14] N4Cu [Ag (CN) 2] 2} .2H2O was characterized by means of elemental analysis, infrared spectrum and ultraviolet spectrum.