The major solving ways for the material wear are surface modification and lubrication.Currently,the researches at home and abroad are all limited to the single study of either nano-lubricating oil additive or electroless deposited coating.The surface coating has high hardness and high wear resistance,however,the friction reduction performance of the coating with high hardness is not good,the thickness of the coating is limited,and the coating can not regenerate after wearing.The nano-lubricating additives have good tribological performance and self-repair function,but under heavy load,the self-repair rate to the worn surface with the nano-additives is smaller than the wearing rate of the friction pair.To solve the above problems,the Ni-W-P alloy coating and deposition process with excellent anti-wear,and suitable for industrial application were developed,the optimum bath composition and process can be obtained by studying the influence of the bath composition,temperature and PH value to the deposition rate and the plating solution stability.The tribological properties as well as anti-wear and friction reduction mechanism of wear self-repair nano-ceramic lubricating additives are also studied.The ring-block abrasion testing machine and energy dispersive spectrometer are used to explore the internal relation between the coating and the nano-lubricating oil additives,and the tribology mechanism,to seek the synergetic effect between the two.The test results show that the wear resistance of Ni-W-P alloy coating(with heat treatment and in oil with nano-ceramic additives) has increased hundreds times than 45 steel as the metal substrate in basic oil,the friction reduction performance is improved.This research breaks through the bottleneck of previous separate research of the above-mentioned two methods,and explores the combination use of the two methods in industrial field. The major solving ways for the material wear are surface modification and lubrication. Current, the researches at home and abroad are all limited to the single study of either nano-lubricating oil additive or electroless deposition coating. The surface coating has high hardness and high wear the friction reduction performance of the coating with high hardness is not good, the thickness of the coating is limited, and the coating can not regenerate after wearing. The nano-lubricating additives have good tribological performance and self-repair function, but under heavy load, the self-repair rate to the worn surface with the nano-additives is smaller than the wearing rate of the friction pair. To solve the above problems, the Ni-WP alloy coating and deposition process with excellent anti-wear , and suitable for industrial application were developed, the optimum bath composition and process can be obtained by studying the influence of the bath composition, temperature and PH value t The deposition rate and the plating solution stability. The tribological properties as well as anti-wear and friction reduction mechanism of wear self-repair nano-ceramic lubricating additives are also studied. The ring-block abrasion testing machine and energy dispersive spectrometer are used to explore the internal relation between the coating and the nano-lubricating oil additives, and the tribology mechanism, to seek the synergetic effect between the two. test results show that the wear resistance of Ni-WP alloy coating (with heat treatment and in oil with nano-ceramic additives) has increased hundreds times than 45 steel as the metal substrate in basic oil, the friction reduction performance is improved. This research breaks through the bottleneck of previous separate research of the above-mentioned two methods, and explores the combination use of the two methods in industrial field.