光透薄层电极(OTTLE)在给定的电位下可测定介稳化合物的可见光谱,我们首次将它用于CO_2电催化还原机理的研究,并检测到CO_2钴卟啉配合物中间体和确定了催化机理。 光透薄层电极池的工作电极是甩0.01mm金丝网,面积为0.5×2.0cm~2,网孔密度为每厘米宽度内约含100根金丝。对电极为园铂片,参比电极为SCE,鲁金毛细管穿过 For the first time, OTTLE was used to study the mechanism of CO 2 electrocatalytic reduction and to detect the CO 2 cobalt porphyrin complex intermediates and to determine The catalytic mechanism. Light through the electrode layer electrode working electrode rejection 0.01mm gold wire mesh, an area of ​​0.5 × 2.0cm ~ 2, mesh density per centimeter width containing about 100 gold wire. On the electrode Park platinum, reference electrode for the SCE, Lu Jin capillary through