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The new uranyl complex UO2(NO3)2[PhN(CH3)C(O)(CH3)NPh]2 was synthesized and its crystal structure has been determined by single-crystal X-ray diffraction. Crystal data: C30H32N6O10U, triclinic, space group P with a = 7.772(1), b = 9.267(1), c = 12.644(1) ? a = 68.246(8), b = 73.871(9), g = 84.99(1)o, V = 812.4(2) ?, Mr = 874.65, Z = 1, Dc = 1.788 g/cm3, F(000) = 426, m = 5.062 mm-1, the final R = 0.022 and wR = 0.059 for 3571 observed reflections (I > 2s(I)). The central uranyl ion is coordinated by six oxygen atoms, two from the carbonyl groups of N,N-dimethyl-N,N-dibenzenyl-urea molecules and the other four from two nitrate groups.
The new uranyl complex UO2 (NO3) 2 [PhN (CH3) C (O) (CH3) NPh] 2 was synthesized and its crystal structure has been determined by single-crystal X- ray diffraction. Crystal data: C30H32N6O10U, triclinic, space group P with a = 7.772 (1), b = 9.267 (1), c = 12.644 (1)? a = 68.246 (8), b = 73.871 (9), g = 84.99 (1) o, V = 812.4 The final R = 0.022 and wR = 0.059 for 3571 observed reflections (I> 2s), Mr = 874.65, Z = 1, Dc = 1.788 g / cm3, F (000) = 426, m = 5.062 mm- (I)). The central uranyl ion is coordinated by six oxygen atoms, two from the carbonyl groups of N, N-dimethyl-N, N-dibenzenyl-urea molecules and the other four from two nitrate groups.