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本文首先对二环戊二烯基二氯化锆(CP_2ZrCl_2)的合成方法进行了评选,作者认为由环戊二烯基锂与四氯化锆反应是一种较好的合成方法,然后,以CP_2ZrCl_2为原料与取代苯酚反应合成了二个新化合物CP_2Zr(OC_6H_3Me_2-3,5)_2、CP_2Zr(OC_6H_3Me_2-2,4)_2.文中给出了它们的红外光谱图和核磁共振谱图,同时,研究了它们与亲电试剂如HCl、CH_3-C-C1、SOCl_2等的反应性能,这类研究尚未见报导。
In this paper, the synthesis method of dicyclopentadienyl zirconium dichloride (CP_2ZrCl_2) was first selected. The authors believe that the reaction of cyclopentadienyl lithium and zirconium tetrachloride is a good method of synthesis. Then, CP_2ZrCl_2 as raw materials and substituted phenol were synthesized two new compounds CP_2Zr (OC_6H_3Me_2-3,5) _2, CP_2Zr (OC_6H_3Me_2-2,4) _2.In the paper, their infrared spectra and nuclear magnetic resonance spectra were given, at the same time, Their reactivity with electrophiles such as HCl, CH_3-C-C1, SOCl_2 and so on have been studied. Such studies have not been reported yet.