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金属卟啉化学是现代化学中重要的分支之一。在自然界,金属卟啉(类似物)配合物构成了叶绿素、血红蛋白及细胞色素等生物大分子的核心部分,参与生物体内信使气体分子的体内传输过程。本文综述了不同的金属卟啉配合物(MP)与气体小分子(O2,COx,NOx,H2S等)的相互作用,此类作用对于气体小分子在体内的结合及运输起着重要的作用,同时为工业过程的设计及生物模拟提供了依据。随着在生物医学、能源、分析化学、合成催化、材料科学以及气体的传输和固定等方面的广泛应用,新型MP的设计合成、结构特点和性质研究将得到不断发展。
Metalloporphyrins are one of the most important branches in modern chemistry. In nature, metalloporphyrins (analogs) complexes form the core of biological macromolecules such as chlorophyll, hemoglobin and cytochromes and are involved in the in vivo transmission of messenger gas molecules in organisms. This review summarizes the interactions between different metalloporphyrin complexes (MPs) and small gas molecules (O2, COx, NOx, H2S, etc.), which play an important role in the binding and transport of small gas molecules in the body. At the same time for the industrial process design and biological simulation provides the basis. With the extensive application in biomedicine, energy, analytical chemistry, synthesis and catalysis, materials science and gas transmission and fixation, the design, synthesis, structural characteristics and properties of the new MP will be continuously developed.