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用动电位极化曲线和恒电位暂态电流方法研究了EDTA对碱性溶液中Cl-引起铁孔蚀的抑制作用。结果表明,极低浓度的EDTA能阻抑Cl-引起铁孔蚀,原因在于EDTA能与Fe3+形成非常稳定的络合物FeY-,抑制了腐蚀产物FeCl3的形成。
The potentiodynamic polarization curve and potentiostatic transient current method were used to study the inhibitory effect of EDTA on Cl-induced iron pitting corrosion in alkaline solution. The results show that very low concentration of EDTA can suppress Cl - -induced iron pitting corrosion because EDTA can form a very stable FeY- complex with Fe3 + and inhibit the formation of the corrosion product FeCl3.