In this paper, the 18 O distribution of surface water from the central sea areas of the Bering Sea and the Chukchi Sea was studied. The δ 18 O value of surface water from the Bering Sea is averagely -0.5‰; the δ 18 O contents of the Chukchi Sea are distributionally lower in northeast and higher in southwest; the δ 18 O value at the margin of Canadian Basin is -2.8‰, and averagely -0.8‰ in the southern area of the Chukchi Sea. The δ 18 O vertical distribution in some deep water stations from the Chukchi Sea and the Bering Sea is also studied. In the southern margin of Canadian Basin, the δ 18 O value is -2‰ -3‰ for surface layer and rises to 0 at 100 m depth layer. In the Bering Sea, the δ 18 O is about -0.5‰ for surface layer and increases to 0 at the depth of 300 m. The NO tracer can reflect obviously three water masses vertically distributed in the central Bering Sea: the upper Bering water mass, the middle Bering water mass and the deep Pacific water mass. The distributive ranges of NO and temperature for the various water masses are T<7℃, NO>780 μmol/dm 3 and T≥7℃, NO>650 μmol/dm 3 for upper Bering water mass, T<4℃, 550 780 μmol / dm 3 and T ≥ 7 ° C, NO> 650 μmol / dm 3 for upper Bering water mass , T <4 ° C, 550