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在配体存在下，通过金属铜粉和过氧化苯甲酰的氧化加成反应合成了双核铜配合物［Ｃｕ（Ｃ６Ｈ５ＣＯＯ）２（Ｃ５Ｈ６Ｎ２）］２·，以元素分析、电导、热重－差热分析、红外光谱、磁性及粉末衍射对配合物进行了表征，并经Ｘ－射线单晶结构分析，确定了配合物的结构，晶体属于三斜晶系，空间群为Ｐ—１，分子式为Ｃ４６Ｈ４８Ｎ４Ｏ１０Ｃｕ２，Ｍｒ＝９４３．９３，ａ＝１０．８０６（１）ｋｂ＝１１．１６９（３），Ｃ＝１１．７２９（２）Ａ，α＝７１．９９（２），β＝８９．３８（１），γ＝８１．３７（１）°，Ｖ＝１３３０．１Ａ３，Ｄｃ＝１．１７２ｇ／ｃｍ３，Ｒ＝０．０４３２９，Ｒｗ＝０．０４８６０，Ｆ（０００）＝４９０，μ＝８．５ｃｍ－１，Ｚ＝１，两个铜原子的配位环境相同，由羧酸根的四个氧原子和２－氨基吡啶的氮原子形成五配位的四方锥多面体。
In the presence of a ligand, the binuclear copper complex [Cu (C6H5COO) 2 (C5H6N2)] 2 · was synthesized by the oxidative addition reaction of metal copper powder and benzoyl peroxide. The elemental analysis, conductivity, The complex was characterized by means of thermal analysis, IR, magnetic and powder diffraction. The structure of the complex was confirmed by X-ray single crystal structure analysis. The crystal belongs to triclinic system with space group P-1 and molecular formula A = 10.806 (1) kb = 11.169 (3), C = 11.729 (2) A, α = 71.99 (2), β = 89.38 (3) C46H48N4O10Cu2, Mr = 943.93, 1, γ = 81.37 (1) °, V = 1330.1A3, Dc = 1.172 g / cm3, R = 0.04329, Rw = 0.04860, F (000) = 490, μ = 5cm-1, Z = 1, the two copper atoms with the same coordination environment, the four oxygen atoms of the carboxylate and - aminopyridine nitrogen atom form a five-coordinate square-pyramidal polyhedron.