E)-α-Aryltellurenylvinylstannanes have been synthesized stereoselectively via the hydrozirconation of alkynyl- stannanes, followed by the reactions with aryltellurenyl iodides. (E)-α-Aryltellurenylvinylstannanes can undergo sequential cross coupling reactions with both electrophiles and nucleophiles in the presence of transition metal complexes to form two carbon-carbon bonds in the same olefinic carbon leading to trisubstituted alkenes stereose- lectively. E) -α-Aryltellurenylvinylstannanes have been stereoselectively via the hydrozirconation of alkynyl-stannanes, followed by the reactions with aryltellurenyl iodides. (E) -α-Aryltellurenylvinylstannanes could subsequently sequential cross coupling reactions with both electrophiles and nucleophiles in the presence of transition metal complexes to form two carbon-carbon bonds in the same olefinic carbon leading to trisubstituted alkenes stereosective.