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The correlation between shape and size of linear chains on the simple cubic lattice is investigated using a dynamicMonte Carlo technique. A positive correlation between the asphericity parameter A and the square of the end-to-end distanceR~2, as well as that between A and the square of the radius of gyration S~2, is found for both RW and SAW chains, indicatingthat a chain conformation of small size is usually more spherical than one of large size. The result can explain why the shapeof the SAW chain deviate much more from a sphere than that of the RW chain, and can also explain the similar dependenceof size and shape on chain stiffness and on the distance of the first bead of a chain from an infinitely large flat surface.
The correlation between shape and size of linear chains on the simple cubic lattice is investigated using a dynamic Monte Carlo technique. A positive correlation between the asphericity parameter A and the square of the end-to-end distance R ~ 2, as well as that between a and the square of the radius of gyration S ~ 2, is found for both RW and SAW chains, indicating that a chain conformation of small size is usually more spherical than one of large size. The result can explain why the shape of the SAW chain deviate much more from a sphere than that of the RW chain, and can also explain the similar dependence of size and shape on chain stiffness and on the distance of the first bead of a chain from an infinitely large flat surface.