介绍了制备水溶性杯芳烃的方法,主要是在杯芳烃上引入磺酸基、氨基、羧基等亲水基团。详细论述了水溶性杯芳烃与过渡金属、稀土金属等金属离子的配合作用,包括阳离子-π作用、π-π作用、静电作用等,根据这些性质,对水溶性杯芳烃配合金属离子的应用前景做了展望。 A method for preparing water-soluble calixarene is introduced, mainly introducing sulfonic acid group, amino group, carboxyl group and other hydrophilic groups into calixarene. In this paper, the coordination between water-soluble calixarene and metal ions such as transition metal and rare earth metal is discussed in detail, including cation-π interaction, π-π interaction and electrostatic interaction. According to these properties, Made a look.