Synthesis and Characterization of Two Binuclear Macrocyclic Zinc（Ⅱ） Complexes by Anion Exchange

来源 :结构化学 | 被引量 : 0次 | 上传用户：jacychang

【摘要】

：

Two macrocyclic zinc(II) complexes {[ZnL(VO3)2]·0.33H2O}n(1) and [ZnL(H2O)2][Ni(CN)4](2)(L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) h

【作者】

：

OU Guang-Chuan HUANG Zhong-Wen

【机构】

：

DepartmentofBiologyandChemistry,KeyLaboratoryofFunctionalOrganometallicMaterialsofHunanProvinceColle

【出处】

：

结构化学

【发表日期】

：

2014年6期

【关键词】

：

配合物阴离子交换单晶X射线衍射分析锌双核合成表征三维结构 macrocyclic zinc（Ⅱ） complexes binuclear vana

【基金项目】

：

supported by the Project for Undergraduate Research Study and Innovative Experiment of Hunan Provincial（2013-191）, National Undergraduate Training Programs for Innovation and Entrepreneurship（20131055

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论文部分内容阅读

Two macrocyclic zinc(II) complexes {[ZnL(VO3)2]·0.33H2O}n(1) and [ZnL(H2O)2][Ni(CN)4](2)(L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) have been obtained from the reactions of [ZnL](ClO4)2 with NH4VO3 and K2[Ni(CN)4], respectively,

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