binuclear相关论文
Solvothermal Synthesis,Crystal Structure and Characterization of a New Binuclear Nickel(Ⅱ)Complex wi
A new binuclear nickel(Ⅱ)complex[Ni2(MBBA)2(HPT)2(H2O)2]·2H2O(1)was synthesized with nickel hydroxide,2-(4-methylbenzo......
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Binuclear manganese complex [(bipy)2Mn2(μ-O)(μ-Ac)2(H2O)2](CIO4)2 was synthesized by the reaction of MnAc3 · 2H2O......
In the medium of H2O, C2H5OH and HAC, the reaction of Gd(NO3)3-6H2O with C6H5COONa and C12H8N2 produced a novel binuclea......
This paper reports the synthesis,properties and crystal structure of the title model compound with the ESR parameters g<......
Exogenous bridge and tautomer effects on magnetic interaction of binuclear copper(II) complexes of μ
Four enol-form binuclear copper complexes with different exogenous bridges, [Cu2(L)(μ-Cl)] (1), [Cu(L)(μ-N3)]· DM......
Dimeric complex 〔Cu(SbPh 3) 2I〕 2 has been synthesized by a solid state reaction at a low heating temperature and i......
Synthesis, Crystal Structure and MMCT Property of a New Mixed-valence Cyanide-bridged Binuclear Comp
本文通过对荣华二采区10...
本文通过对荣华二采区10...
Ethylene Polymerization by a Novel Dinuclear Heteroligated Titanium Complex with the Ligand of (Sali
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本文通过对荣华二采区10...
Binuclear Aluminum Complexes Supported by Linked Bis(β-diketiminate) Ligands for Ring-Opening Polyme
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Ethylene Polymerization by a Novel Dinuclear Heteroligated Titanium Complex with the Ligand of (Sali
The condensation of acetylacetone (CH3COCH2COCH3) with benzdine(H2N-C6H4-C6H4-NH2) yielded diimine ligand 1 [HOC(Me)C(H)......
A new binuclear complex [Cu2L(OH)](ClO4)3·2H2O has been synthesized and characterized, where L=2,6-bis{[bis-(2-aminoeth......
A binuclear copper(Ⅰ) complex [Cu2(dppm)2(C7H6N2)2](NO3)2 (C7H6N2 = benzimidazole, dppm = Ph2PCH2PPh2) has been synthes......
Synthesis, Characterization and Biological Activities of Binuclear Metal Complexes of 2-Benzoylpyrid
The Schiff base, 1-phenyl-1-(pyridin-2-yl)-N-(pyrimidin-2-yl)methanimine dihydrate (L<sub>1</sub>) has been synthesized ......
为了得到稳定性更好、活性更高的烯烃复分解催化剂,本文采用有机合成的方法,以钌卡宾烯烃复分解催化剂为主体,用锌卟啉进行修饰,得......
本文以金属铜粉为起始原料，利用氧化加成反应，合成了６个新的羧酸桥联双核铜配合物：［Ｃｕ（Ｃ６Ｈ５ＣＯＯ）２Ｌ］２［Ｌ＝２—氨基吡啶（１），２—甲基吡啶（２），２，４，６—三甲基吡啶（３），三苯基氧化膦（４），喹啉......
以N,N′-二(2-氨乙基)草酰胺合镍(Ⅱ)Ni(oxen)为单核片断合成了桥联双核配合物[Ni(oxen)Cu(bpy)2](ClO4)2@H2O,通过元素分析、摩尔......
The reaction of NdCl<sub>3</sub> with NaC<sub>5</sub>Me<sub>5</sub> generates a novel complex （C<sub>5</sub>Me<sub>5</sub......
硅氧硅桥链的双核茂钛催化剂用于乙烯聚合的研究冯茹苏立明贺大为（中国科学院化学研究所北京１０００８０）王佰全田公路许善生周秀中（南开大......
合成了以TTFA、1，10-Phen为第一和第二配体的系列铕和钐、铽（用Re表示钐、铕）双核稀土有机配合物Re1-xTbx（TTFA）3Phen，测试了不同掺杂浓......
Electronic and molecular structures of [(X)mMn(μ-oxo)2Mn(Y)n]q+ (X, Y = H2O, OH and O), which are Mn cluster models at ......
A direct method of obtaining complexes of cobalt with respect to rare earth elements is reported. The total of 14 new co......
采用水热法合成了一种新型双核铅（Ⅱ）配合物[Pb2（CA）4（Medpq）2]（HCA=cinnamic acid, Medpq=2-methyldipyrido[3,2-f：2,3＇-h]quinoxaline），并对......
采用芳基亚胺桥联双核茂钛络合物催化乙烯聚合反应,考察了茂环上不同取代基、聚合温度、聚合时间和助催化剂用量对络合物催化活性......
Syntheses and Magnetism of Binuclear Tb(Ⅲ)-Tb(Ⅲ)Complexes with Dianion of Chloranilic Acid as Bridgi
The syntheses, spec(?) complexes are of significance for understanding mechanisms of magnetic interaction between metal ......
Synthesis, structures, and properties of two new binuclear complexes based on carboxyl-substituted n
Two new binuclear complexes, [M2(μ-NITpBA)4(H2O)2] (M = Zn 1 and Cu 2) [where NIpBA =?2-(4-carboxyl-phenyl)-4,4,5,5-tet......
Microwave Preparation and Spectroscopic Investigation of Binuclear Schiff Base Metal Complexes Deriv
The binuclear Schiff base complexes prepared by condensation 2,6-diamino-pyridine and salicylaldehyde (LH) by using micr......
Spectroscopic Evaluation of the Molecular Structures of di-μ-Chlorobis(1,5-Cyclooctadiene) Iridium (
Vibrational and H-NMR spectroscopic studies on di-μ-chlorobis(1,5-cyclooctadiene) of iridium(I) and rhodium (I) complex......
<正> 自从1954年Wilkinson等人首次合成三茂稀土配合物以来,已有不少类型的二茂稀土配合物见诸报道,但都是单核的。双核三茂型稀土......
合成了新化合物（Ｎ２Ｈ６）０．５〔（ＣＨ３）４Ｎ〕｛ＭｏＯ（Ｈ２Ｏ）Ｃ２Ｏ４〕２（ｕ２－Ｏ）２｝·Ｈ２Ｏ，并运用元素分析、红外和单晶Ｘ衍射对其结构进行了表征。测定结果证实该化合物有两个共边连接的钼氧八面......
以醋酸铜、邻氯苯甲酸（o-CBA）和2,2′-联吡啶（2,2′-bipy）为原料在甲醇水介质中通过水热反应,合成了1个新的五配位的双核铜髤配合物[Cu......
A Y3+ complex with triethylenetetraaminehexaacetic acid was prepared and its composition and structure were determined a......
Ab Initio Molecular Orbital Calculation on Dinuclear Gold(Ⅰ)Complexes──Metal-Metal Interaction and E
ＡｂＩｎｉｔｉｏＭｏｌｅｃｕｌａｒＯｒｂｉｔａｌＣａｌｃｕｌａｔｉｏｎｏｎＤｉｎｕｃｌｅａｒＧｏｌｄ（Ⅰ）Ｃｏｍｐｌｅｘｅｓ——Ｍｅｔａｌ┐ＭｅｔａｌＩｎｔｅｒａｃｔｉｏｎａｎｄＥｌｅｃｔｒｏｎｉｃＳｔｒｕｃｔｕｒｅｏｆＢｉｎｕｃｌｅａｒＧｏｌｄ（Ⅰ.........
Synthesis and X－ray Structure of a Binuclear Nickel（Ⅱ） Complex of Nickel（Ⅱ） Perchlorate and 2，2＇－Bip
ＳｙｎｔｈｅｓｉｓａｎｄＸ－ｒａｙＳｔｒｕｃｔｕｒｅｏｆａＢｉｎｕｃｌｅａｒＮｉｃｋｅｌ（Ⅱ）ＣｏｍｐｌｅｘｏｆＮｉｃｋｅｌ（Ⅱ）Ｐｅｒｃｈｌｏｒａｔｅａｎｄ２，２＇－ＢｉｐｙｒｉｄｙｌｗｉｔｈＮ，Ｎ＇－Ｂｉｓ（２－ａｍｉｎｏｅｔｈｙｌ）ｏｘａｍｉｄ.........
Synthesis and Characterization of Binuclear Lanthanide Complexes with Macrocyclic Schiff Base Derive
Nine homobinuclear lanthanide complexes with macrocyclic Schiff base were prepared by condensing 2, 6-diacetylpyridine a......
Ｐｈｔｈａｌｏｃｙａｎｉｎｅｓｈａｖｅｂｅｅｎｉｎｔｅｎｓｉｖｅｌｙｓｔｕｄｉｅｄｂｅｃａｕｓｅｔｈｅｙｅｘｈｉｂｉｔｍａｎｙｏｕｔｓｔａｎｄｉｎｇｃｈｅｍｉｃａｌａｎｄｐｈｙｓｉｃａｌｐｒｏｐｅｒｔｉｅｓｆｏｒａｐｐｌｉｃａｔｉｏｎｓ［１，２］．Ｍ.........
Seven new binuclear titanocenes with different linking bridges, unsubsti-tuted or substituted on the Cp rings, were synt......
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１ＩＮＴＲＯＤＵＣＴＩＯＮＣｏｐｐｅｒｃｏｍｐｌｅｘｅｓｈａｖｅａｌａｒｇｅｖａｒｉｅｔｙｏｆｓｔｅｒｉｃｓｔｒｕｃｔｕｒｅｓａｎｄｐｌａｙａｎｉｍｐｏｒｔａｎｔｒｏｌｅｉｎｃａｔａｌｙｓｉｎｇｔｈｅｅｎｚｙｍａｔｉｃａｃｔｉｖｉｔｉｅｓ，ｗｈｉｃｈ.........
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A binuclear zinc(Ⅱ) complex with 2-carboxycinnamic acid(2-ccm) and dipyrido-[3,2-a:2′,3′-c]phenazine(DPPZ),{[Zn2(2-cc......
Two macrocyclic zinc(II) complexes {[ZnL(VO3)2]·0.33H2O}n(1) and [ZnL(H2O)2][Ni(CN)4](2)(L = 5,5,7,12,12,14-hexamet......
A new mixed-valence cyanide-bridged complex, Br3Fe(μ-NC)RuBr(dppm)2(dppm = bis(diphenylphosphino)methane), was obtained......
We report here the calculations on electronic structures of mono- and bi-nuclear benzene - transition metal sandwich com......
IntroductionThe expension of the coordination chemistry of polyoxomolybdates is attributed to the solubility of the poly......
