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The supramolecular compound [(AgI3)(4-HBPFA)2(H2O)] (Mr = 1361.11) was synthesized via the reaction of 1,1?-bis[(4-pyridylamino)carbonyl]ferrocene (4-BPFA) with AgI, and structurally characterized by single-crystal X-ray diffraction analysis. Crystal data: monoclinic, space group C2/c, a = 1.6783(3), b = 10.646(2), c = 2.5419(5) ?, β = 93.66(3)o, V = 4532.2(16) ?3, Z = 4, Dc = 1.995 g/cm3, F(000) = 2632 and μ = 3.158 mm-1. The compound consists of (4- HBPFA)+, (AgI3)2- and H2O. In the structure, the adjacent (4-HBPFA)+ are linked by C–H…O and N–H…N hydrogen bonds into 1-D chains which are further linked by C–H…I and N–H…I hydrogen bonds as well as intermolecular π-π stacking interactions to form a 3-D supramolecular compound.
The supramolecular compound [(AgI3) (4-HBPFA) 2 (H2O)] (Mr = 1361.11) was synthesized via the reaction of 1,1- , and structurally characterized by single-crystal X-ray diffraction analysis. Crystal data: monoclinic space group C2 / c, a = 1.6783 (3), b = 10.646 (2), c = 2.5419 (3) o, V = 4532.2 (16)? 3, Z = 4, Dc = 1.995 g / cm3, F000 = 2632 and μ = 3.158 mm-1. The compound consists of (4- HBPFA) (AgI3) 2- and H2O. In the structure, the adjacent (4-HBPFA) + are linked by C-H ... O and N-H ... N hydrogen bonds into 1-D chains which are further linked by C-H I and N-H ... I hydrogen bonds as well as intermolecular π-π stacking interactions to form a 3-D supramolecular compound.