在1-乙基咪唑三氟乙酸盐离子液体中合成的聚吡咯对草酸的电催化氧化(英文)

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The electrochemical oxidation of oxalic acid is important in environmental engineering.In this paper,polypyrrole(PPy)was prepared galvanostatically in an ionic liquid 1-ethylimidazolium trifluoroacetate(HEImTfa)and its electro-catalysis function for the electrochemical oxidation of oxalic acid was investigated by using cyclic voltammetry.The results showed that the electro-catalytic activity of PPy prepared in HEImTfa(PPy-HEImTfa)was greatly improved as compared with that prepared in conventional H_2SO_4 aqueous solution.Therefore,the use of HEImTfa as growth electrolyte and solvent for electro-polymerization of pyrrole resulted in an electrochemically catalytic film of PPy for the electro-oxidation of oxalic acid. The electrochemical oxidation of oxalic acid is important in environmental engineering. In this paper, polypyrrole (PPy) was prepared galvanostatically in an ionic liquid 1-ethylimidazolium trifluoroacetate (HEImTfa) and its electro-catalysis function for the electrochemical oxidation of oxalic acid was investigated by using cyclic voltammetry. The results showed that the electro-catalytic activity of PPy prepared in HEImTfa (PPy-HEImTfa) was greatly improved as compared with that prepared in conventional H 2 SO 4 aqueous solution. Before, the use of HEImTfa as growth electrolyte and solvent for electro -polymerization of pyrrole resulted in an electrochemically catalytic film of PPy for the electro-oxidation of oxalic acid.
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